Electrochemical Decarboxylative Hydroxylation for the Sustainable Synthesis of Bempedoic Acid - Copy

Electrochemical Decarboxylative Hydroxylation for the Sustainable Synthesis of Bempedoic Acid - Copy

A sustainable synthesis of bempedoic acid is achieved using electrochemical hydroxylative decarboxylation as the key step.

The Laurencia Stereochemical Paradox: Chemical Shift Litmus Test, Asymmetric Total Synthesis, and Structural Reassignment of (+)-Itomanallene B

The Laurencia Stereochemical Paradox: Chemical Shift Litmus Test, Asymmetric Total Synthesis, and Structural Reassignment of (+)-Itomanallene B

Itomanallene B-type metabolites have presented a stereochemical paradox, as Laurencia intricata and Laurencia nangii yield epimeric structures despite sharing the same planar connectivity.